Abstract
COACERVATE RHEOLOGY: APPLICATIONS OF DYNAMICS

Partha Sarathi Roy*

ABSTRACT

Investigation of the mechanisms of complex formation between polyelectrolytes and oppositely charged colloids, and of coacervate structures formed at different length scales represents an active and important research area. Although mechanisms of coacervation have been deduced from observations of self-organized microscopic structures, the true relationship between coacervation mechanism and the resultant structure remains to be further explored. There is still a need for more connection between experimental and theoretical work. Experimental efforts have largely focused on phase behavior as the primary point of comparison, however this is not always a direct probe of the molecular-level features such as charge correlations, charge density effects, excluded volume, and specific ion effects. This makes it difficult to distinguish between VO theory and more sophisticated theories, which as a result are not often compared to experiment.

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